Why sodium methallyl sulfonate(SMAS-based flocculants maintain stable performance in high-salinity wastewater (TDS>100000 ppm) while conventional cationic flocculants fail

Why sodium methallyl sulfonate(SMAS-based flocculants maintain stable performance in high-salinity wastewater (TDS>100000 ppm) while conventional cationic flocculants fail

Conventional cationic flocculants easily lose efficacy under ultra-high salinity: inorganic ions shield surface charge, cause molecular chain curling and weaken electric neutralization and bridging ability.

SMAS-based flocculant vs conventional cationic flocculant

By contrast, SMAS-based flocculants remain excellent flocculation performance for these reasons:

  1. High-polarity sulfonate groups possess strong anti-shielding capacity, maintaining stable charge activity even at TDS over 100000 ppm.
  2. Methyl branched chains provide steric hindrance to keep polymer chains stretched without curling in high-salt water.
  3. Stable copolymer structure resists erosion of calcium, magnesium and high-concentration chloride ions, avoiding degradation and precipitation.
  4. It relies on multiple mechanisms including hydrogen bonding, hydrophobic association and sweeping flocculation, not only electric neutralization.
  5. Stable hydration film resists salting-out effect, preventing polymer separation and performance attenuation under extreme salinity.

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