Operational Guidelines for Using Sodium Methallyl Sulfonate (SMAS) as a Fluid Loss Additive

Operational Guidelines for Using Sodium Methallyl Sulfonate (SMAS) as a Fluid Loss Additive

I. Product Selection and Preparation

  1. Specification Requirements:
  • Select industrial-grade SMAS with purity ≥95%
  • Confirm absence of metal impurities like Fe³⁺ (content ≤0.5ppm)
  1. Mother Solution Preparation:

Chemical

SMAS: 3-5% (mass fraction)
Acrylamide (AM): 5-8%
Deionized water: Balance
Initiator (ammonium persulfate): 0.05-0.1%

*Note: React with stirring at 50-60°C for 4-6 hours to prepare copolymer mother solution*

II. Drilling Fluid System Compatibility

Fluid TypeRecommended DosageApplicable pH RangeTemperature Limit
Freshwater0.3-0.5%7-9120°C
Brine0.5-0.8%8-10150°C
Saturated Brine0.8-1.2%9-11180°C

III. Field Operation Procedures

  1. Pretreatment:
  • Measure base fluid API filtration loss (baseline)
  • Adjust pH to 8.5-9.5 (using Na₂CO₃ or NaOH)
  1. Dosing Procedure:
    ① Slowly add SMAS copolymer under low-speed agitation (500rpm)
    ② Continue mixing for 30 minutes to ensure complete dispersion
    ③ Test performance after 24-hour aging
  2. Performance Monitoring Indicators:
  • API filtration loss: Control ≤15ml/30min
  • HTHP filtration loss (150°C): ≤25ml/30min
  • Rheological parameters: Maintain PV at 8-15cP, YP 3-8lb/100ft²

IV. Key Considerations

  1. Compatibility Testing:
  • Conduct compatibility tests with common additives (e.g. PAC-LV, SMP)
  • Avoid direct mixing with high-valence metal salts (Al³⁺, Cr³⁺)
  1. Performance Enhancement:
  • Combine with 0.1-0.3% nano-SiO₂ to improve thermal stability
  • Add 0.05% EDTA to enhance salt resistance
  1. Troubleshooting:

Issue:

Possible causes:
1. System pH<7 causing sulfonate protonation
2. Temperature exceeding 180°C causing degradation
Solutions:
1. Add NaOH to adjust pH
2. Supplement with 0.2% sulfonated phenolic resin

V. Environmental Management

  1. Waste treatment:
  • Control waste liquid COD <500mg/L (treatable by Fenton oxidation)
  1. Biotoxicity:
  • 96h LC50 (fish) >1000mg/L, classified as low-toxicity substance

Note: Specific parameters should be adjusted according to formation conditions. Pilot testing is recommended prior to field application.

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