Introduction to Sodium Allyl Sulfonate(SAS)(CAS Number: 2495-39-8)

Introduction to Sodium Allyl Sulfonate(SAS)(CAS Number: 2495-39-8)

Chemical & Physical Properties

  • IUPAC Name: Sodium prop-2-ene-1-sulfonate
  • Molecular Formula: C₃H₅NaO₃S
  • Molecular Weight: 144.12 g/mol
  • Appearance: White to light yellow crystalline powder
  • Solubility: Highly soluble in water (>500 g/L at 20°C), insoluble in nonpolar solvents.
  • Melting Point: ~300°C (decomposes)
  • pH (1% solution): 7–9

Key Features

  1. Dual Functional Groups:
    • Allyl group (–CH₂CH=CH₂): Enables free-radical polymerization (e.g., with acrylamide or styrene).
    • Sulfonate group (–SO₃⁻Na⁺): Provides hydrophilicity and anionic charge, enhancing water solubility and anti-precipitation properties.
  2. Chemical Stability:
    • Resistant to hydrolysis and oxidation in aqueous solutions.
    • Compatible with acids, alkalis, and hard water.

Industrial Applications

1. Polymer Industry

  • Copolymerization Monomer: Used to synthesize:
    • Water-soluble polymers (e.g., for flocculants in wastewater treatment).
    • Ion-exchange resins (sulfonate groups improve cation-exchange capacity).
  • Modifier: Enhances flexibility and adhesion in acrylic/vinyl polymers.

2. Textile & Dyeing

  • Leveling Agent: Promotes even dye distribution on fabrics (e.g., for reactive dyes).
  • Antistatic Agent: Reduces static buildup in synthetic fibers.

3. Water Treatment

  • Scale Inhibitor: Prevents Ca²⁺/Mg²⁺ scale formation in boilers/cooling systems.
  • Dispersant: Stabilizes suspended particles in industrial water circuits.

4. Surfactants & Emulsions

  • Anionic Surfactant: Used in detergents, emulsifiers, and foaming agents.

5. Electroplating

  • Brightener Additive: Improves smoothness and conductivity of metal coatings.

Safety & Environmental Data

  • Toxicity: Low acute toxicity (LD₅₀ oral, rat: >2000 mg/kg).
  • Handling: Avoid dust inhalation; use PPE (gloves, goggles).
  • Biodegradability: Readily biodegradable (>60% in 28 days per OECD 301B).
  • Regulatory Status: Complies with REACH and EPA standards.

Storage & Packaging

  • Storage Conditions: Keep sealed in a dry, ventilated area at <30°C.
  • Shelf Life: 2 years if stored properly.
  • Packaging: 25 kg woven bags with polyethylene liner or customized options.

Why Choose Sodium Allyl Sulfonate?

  • Combines polymerizability (allyl) and water solubility (sulfonate).
  • Enhances performance in high-salinity or high-temperature environments.
  • Cost-effective alternative to similar sulfonates (e.g., sodium vinyl sulfonate).

For technical specifications or bulk inquiries, please contact suppliers like Haihang Industry or Tokyo Chemical Industry (TCI).